Definition of the Subject
The concept of self‐assembly is today highly popular and frequently used to describe a wide range of phenomena. It is also a conceptthat has a possibility to change the way we produce various types of materials [1]. Self‐assembly can broadly speaking be defined as a process with the followingfeatures [2], where: (i) it involves pre‐existing components, i. e. the components arenot formed by the reaction itself. (ii) the process should be reversible to some extent. (iii) it can be controlled by design.
The supramolecular chemistry approach, pioneered by Jean-Marie Lehn [3], where molecularrecognition is used to assemble supramolecular materials is clearly an important starting point for much of this work. The pre‐existing componentsare usually molecules, amphiphilic species, or oligomeric or polymeric species. However, self‐assembly can also be observed on larger length scalesinvolving e. g. nanoparticles (superlattices) and larger colloidal particles...
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- AI:
-
Ab initio
- AM1:
-
Austin model 1
- AO:
-
Atomic orbital
- B3LYP:
-
Becke's three parameter hybrid LYP functional
- BKL:
-
Bortz–Kalos–Lebowitz
- BO:
-
Born–Oppenheimer
- CA:
-
Cellular automata
- CE:
-
Cluster expansion
- CC:
-
Coupled cluster
- CI:
-
Configuration interaction
- CP:
-
Car‐Parrinello
- DCA:
-
Dynamic cellular automata
- DFT:
-
Density functional theory
- DLVO:
-
Derjaguin–Landau–Verwey–Overbeek
- GGA:
-
Generalized gradient approximation
- HF:
-
1) Hartree–Fock 2) Harris–Foulkes functional
- kMC:
-
kinetic Monte Carlo
- KS:
-
Kohn–Sham
- LbL:
-
Layer-by-layer
- LCAO:
-
Linear Combination of Atomic Orbitals
- LDA:
-
Local density approximation
- LYP:
-
Lee–Young–Parr
- MC:
-
Monte Carlo
- MD:
-
Molecular Dynamics
- MNDO:
-
Modified neglect of differential overlap
- MO:
-
Molecular Orbital
- MP:
-
Møller–Plesset
- NDDO:
-
Neglect of diatomic differential overlap
- NDO:
-
Neglect of differential overlap
- NPT:
-
Isobaric ensemble: constant N, P and T
- NVE:
-
Microcanonical ensemble: constant N, V and E
- NVT:
-
Canonical ensemble: constant N, V and T
- PBC:
-
Periodic boundary conditions
- PF:
-
Phase-field
- PM3:
-
Parametric model 3
- PP:
-
Pseudo‐potential
- PW:
-
Perdew–Wang
- QCA:
-
Quantum‐dot cellular automata
- RSA:
-
Random sequential adsorption
- SA:
-
Self‐assembly
- SAM:
-
Self‐assembled monolayers
- SCF:
-
Self‐consistent field
- STM:
-
Scanning tunneling microscopy
- TB:
-
Tight‐binding
- XC:
-
Exchange correlation
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Acknowledgments
Both authors are connected to the Berzelii centre EXSELENT on porous materials at Stockholm University(http://www.exselent.su.se/).
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Laaksonen, A., Bergström, L. (2009). Self-assembled Materials. In: Meyers, R. (eds) Encyclopedia of Complexity and Systems Science. Springer, New York, NY. https://doi.org/10.1007/978-0-387-30440-3_470
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