Abstract
In this paper, synthesis and characterization of poly(ethylene glycol)- grafted expanded graphite/polyaniline (PEG-grafted EG/PANi) as a novel ecofriendly composite material was reported. EG as substrate prepared from expandable graphite was firstly synthesized by in-situ polymerization at the presence of aniline (An) to obtain EG/PANi, and then graft polymerization with as-prepared PEG-grafted PANi (PEG-g-PANi) composite under no tough conditions. Structural characteristics of the products were evaluated by infrared spectrum (IR), X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis. The experimental results have shown that the product of PEGgrafted EG/PANi composite were synthesized by facile method.
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References
Chung, D.D.L.: Exfoliation of graphite. J. Mater. Sci. 22, 4190–4198 (1987)
Furdin, G.: Exfoliation process and elaboration of new carbonaceous materials. Fuel 77, 479–485 (1998)
Inagaki, M., Tashiro, R., Washino, Y., Toyoda, M.: Exfoliation process of graphite via intercalation compounds with sulfuric acid. J. Phys. Chem. Solids 65, 133–137 (2004)
Celzard, A., Mareche, J.F., Furdin, G., Puricelli, S.: Electrical conductivity of anisotropic expanded graphite-based monoliths. J. Phys. D Appl. Phys. 33, 3094–3101 (2000)
Chen, G.H., Weng, W.G., Wu, D.J., Wu, C.L.: PMMA/graphite nanosheets composite and its conducting properties. Eur. Polym. J. 39, 2329–2335 (2003)
Shimano, J.Y., MacDiarmid, A.G.: Polyaniline, a dynamic block copolymer: key to attaining its intrinsic conductivity. Synth. Met. 123, 251–262 (2001)
Ahmad, R., Kumar, R.: Conducting Polyaniline/Iron Oxide Composite: A Novel Adsorbent for the Removal of Amido Black 10B. J. Chem. Eng. Data 55(9), 3489–3493 (2010)
Chawla, K., Lee, S., Lee, B.P., Dalsin, J.L., Messersmith, P.B., Spencer, N.D.: A novel low-friction surface for biomedical applications: Modification of poly(dimethylsiloxane) (PDMS) with polyethylene glycol(PEG)-DOPA-lysine. J. Biomed. Mater. Res. 90, 742–749 (2008)
Tryba, B., Morawski, A.W., Inagaki, M.: Preparation of exfoliated graphite by microwave irradiation. Carbon 43, 2417–2419 (2005)
Zhu, M.C., Qi, W., Mao, Y.J., Hu, Y., Qing, X., Li, K.Z., Yang, T., Zhang, Y.C., Li, D.X., Chai, H.M.: Synthesis, characterization and adsorption property of expanded graphite-conducting polymer composite. Accepted by Adv. Mater. Res. (2011)
Xiang, C., Li, L.C., Jin, S.Y., Zhang, B.Q., Qian, H.S., Tong, G.X.: Expanded graphite/polyaniline electrical conducting composites_ Synthesis, conductive and dielectric properties. Mater. Lett. 64, 1313–1315 (2010)
Wang, P., Tan, K.L.: Synthesis and Characterization of Poly(ethylene glycol)-Grafted Polyaniline. Chem. Mater. 13(2), 581–587 (2001)
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Zhu, M. et al. (2011). Synthesis and Characterization of Eco-friendly Composite: Poly(Ethylene Glycol)-Grafted Expanded Graphite/Polyaniline. In: Lin, S., Huang, X. (eds) Advances in Computer Science, Environment, Ecoinformatics, and Education. CSEE 2011. Communications in Computer and Information Science, vol 214. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-23321-0_78
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DOI: https://doi.org/10.1007/978-3-642-23321-0_78
Publisher Name: Springer, Berlin, Heidelberg
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