Versatile computer-based instrumentation for the application of three-dimensional voltammetry
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Cited by (5)
Three-dimensional voltammetry: Use of chronoamperometric E-t-i data to achieve second-order advantage
2020, Analytica Chimica ActaCitation Excerpt :It is well known that the resolution between two overlapping voltammetric processes depends largely upon the half-wave potential (E1/2) values, the concentration ratios and the kinetics of the electron transfer [21]. Thus, for example, if two overlapping processes are kinetically different in the context of the electron transfer being the rate determining step, then the multi-time-domain electrochemical measurements could provide a useful way of discriminating against one of the processes, as long as measurements were made at longer time domains [22]. The work presented here aimed at the evaluation of E-t-i data in association with second-order calibration techniques in the development of electroanalytical methods.
Three-dimensional voltammetry assisted by parametric signal fitting: A new perspective for the electrochemical evaluation of metal binding in the presence of electrodic adsorption
2013, Analytica Chimica ActaCitation Excerpt :Although many efforts have been devoted to minimise or modelize this phenomenon [14–21], it still constitutes a serious drawback in the study of metal complexation. In the present work we revisit the methodology of three-dimensional voltammetry, consisting on the measurement of currents vs. potential vs. time by means of consecutive chronoamperograms at increasing potential steps [22–26]. In previous studies such methodology had been mostly applied for qualitative purposes.
EChem++ - An object oriented problem solving environment for electrochemistry. Part 1. A C++ class collection for electrochemical excitation functions
2004, Journal of Electroanalytical ChemistryDynamic Electrochemistry: Methodology and Application
1998, Analytical Chemistry
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Present address: CSIRO Division of Minerals, P.O. Box 124, Port Melbourne, Victoria 3207, Australia.