Summary: We focus on the development of new silicate phosphors for a white LED. In the europium doped silicate system, four LED phosphor candidates-- Li2SrSiO4:Eu2+, Ba9Sc2Si6O24:Eu2+ , Ca3Si2O7:Eu2+ and Ba2MgSi2O7:Eu2+ were found. Luminescent properties under near UV and visible excitation were investigated for the new Eu2+ doped LED silicate phosphors. These new phosphors have a relatively strong absorption band in a long wavelength region.