Network signal coordination control is a crucial means to improve the traffic operation efficiency of the overall roadway network. Accurate identification of critical paths does play an important role in determining the scope of network coordination control. Therefore, this paper proposed the definition of critical path from the perspective of traffic control and management. Under the detection environment of connected vehicle (CV), a comprehensive quantitative indicator system for path criticality evaluation from three aspects, supply side, demand side and operation side, which are arranged in the form of a tower structure. A critical path identification method (CPIM) was then proposed based on the analytic hierarchy process (AHP) theory, which was hereinafter referred to as AHP-CPIM. In order to evaluate the feasibility and effectiveness of the proposed method, a case study set in an urban network in Tongxiang, Zhejiang Province in China, is conducted through simulation models built through VISSIM and Synchro. Two scenarios were set, one is coordination control based on the coordination subarea obtained from Synchro (namely without critical path identification), and another one is coordination control with critical paths obtained from AHP-CPIM. Results showed that, compared with the control of Synchro and Multiband method under the scenario of coordination control without critical path identification, network signal coordination control optimization based on AHP-CPIM improved about 37.9% and 35.9% in average delay, respectively, justifying the effectiveness of CV-driven critical path identification for network signal coordination control.