Based on the analytic network process approach (ANP), a new evaluation method is using for college teaching, namely EM-ANP, is proposed in this paper. Compared with evaluation approaches of traditional college teaching, ES-ANP includes two kinds of steering group criteria and student criteria, and the interdependent relationship between two criteria. The conclusion shows that this kind of teaching evaluation method can reflect the teaching more effective and more accurate, thus play more important role in the evaluation of college teaching.