Baoding national high-tech zone which takes the new energy as the direction is the only one of the 56 national high-tech zones in China, and it has made great progress in recent years. Data envelopment analysis is a linear programming method of assessing the relative effectiveness, it is often used in multiple inputs, multiple output cases, the efficiency of input-output analysis, and scale effect analysis can be carried out. This method excludes a lot of subjective factors, with a strong objectivity, and it has been applied in many areas. In this paper, we used the method of data envelopment analysis, took the national high-tech zones which are not capital-city high-tech national zones like Baoding, collected the 2009 annual financial data, to analyze the industry competitive power of high-tech industry. On basis of the above analysis, we developed countermeasures for high-tech industry of Baoding national high-tech zone.