Wireless networks are undergoing a transformative shift, driven by the crucial factors of cost-effectiveness and sustainability. Digital coding metasurfaces (DCMs) might play a key role in realizing cost-effective digital modulators by harnessing energy embedded in electromagnetic waves traversing through the air. Integrated sensing and communication (ISAC) optimizes power and spectral resources by combining sensing and communication functionalities on a shared hardware platform. This article presents a tutorial-style overview of the applications and advantages of DCMs in ISAC-based networks. Emphasis is placed on the dual functionality of ISAC, necessitating the design of DCMs with simultaneously transmitting and reflecting (STAR) capabilities for comprehensive space control. Additionally, the article explores key signal processing challenges and outlines future research directions stemming from the convergence of ISAC and emerging STAR-DCM technologies.