As economic and social activities continue to increase, transportation is increasingly contributing to climate change, air pollution and other environmental damage. The growing concerns about the sustainability of transportation are forcing everyone in this field to think about solutions to keep our mobility environmentally, economically and socially sustainable. To provide a forum for the exchange of ideas and experiences from industry, academia and the public sector, we have recently held a series of seminars and the first Distributed/Decentralized Hybrid Workshop on Sustainability for Transportation and Logistics (DHW-STL), part of Distributed/Decentralized Hybrid Symposia on Sustainability for Transportation and Logistics (DHS-STL), and Distributed/Decentralized Hybrid Conferences on Sustainability for Transportation and Logistics (DHC-STL). This letter provides a brief report of the First DHW-STL and discusses the potentials, possibilities and perspectives driven by Intelligent Vehicles (IV) technologies to achieve sustainable intelligent systems for transportation and logistics.