The metallic waveguide is one of many effective media for millimeter- and submillimeter-waves because of the advantage of its low-loss nature. This paper describes the fabrication method of PTFE-filled waveguide components with the use of the SR (synchrotron radiation) direct etching process of PTFE, sputter deposition of metal, and electroplating. PTFE is known as a difficult material to process with high precision. However, it has been reported that PTFE microstructures can be fabricated by the direct exposure to SR. First, an iris-coupled waveguide BPF with 5-stage Chebyshev response is designed and fabricated for the Q-band. It is demonstrated that the present process is applicable for the fabrication of the practical components inclusive of narrow patterns. Then, a cruciform 3dB coupler with air-filled posts is designed and fabricated for the Q-band. Directivity and matched state of the coupler can be realized by “holes” in the dielectric material. The measurement results are also shown.