In this letter, the cumulative distribution function (CDF) for the maxima of the OSTBC-MIMO channel capacity in a temporal interval is estimated using the first-order Rice series approximation. As the estimation of the maxima distribution using the Rice series is applicable only to Gaussian random processes, the Gaussian-approximated probability density function (PDF) for the OSTBC-MIMO channel capacity is derived from existing exact PDF (non-Gaussian). The resulting CDF for the maxima capacity is useful to design OSTBC-MIMO systems.