In recent wireless communication systems, security is ensured mainly in the upper-layer techniques such as a password or a cryptography processing. However, security needs not be restricted to the upper-layer and the addition of physical-layer security also would yield a much more robust system. Therefore, in this paper, we exploit chaos communication and propose a chaos multiple-input multiple-output (MIMO) transmission scheme which achieves physical-layer security and additional channel-coding gain. A chaotic modulation symbol is multiplied to the data to be transmitted at each MIMO antenna to exploit the MIMO antenna diversity, and at the receiver, the joint MIMO detection and chaos decoding is done by maximum likelihood decoding (MLD). The conventional chaos modulation suffers from bit error rate (BER) performance degradation, while the coding gain is obtained in the proposed scheme by the chaos modulation in MIMO. We evaluate the performances of the proposed scheme by an analysis and computer simulations.