RFID (Radio Frequency Identification) technology is expected to be used as a localization tool. By the localization of RFID tags, a mobile robot equipped with an RFID reader can recognize the surrounding environment. In this paper, we propose a novel effective scheme called the communication range recognition (CRR) scheme for localizing RFID tags. In this scheme, an RFID reader determines the boundaries of the communication range when it is appropriately positioned by the robot. We evaluate the estimated position accuracy through numerous experiments. We show that the moving distance of the RFID reader in the proposed scheme is lower than that in conventional schemes.