The present paper introduces a novel method for the construction of a class of sequences that have a zero-correlation zone. For the proposed sequence set, both the cross-correlation function and the side lobe of the auto-correlation function are zero for phase shifts within the zero-correlation zone. The proposed scheme can generate a set of sequences of length 8n² from an arbitrary Hadamard matrix of order n and a set of 2n trigonometric-like function sequences of length 4n. The proposed sequence construction can generate an optimal zero-correlation zone sequence set that satisfies the theoretical bound on the number of members for the given zero-correlation zone and sequence period. The auto-correlation function of the proposed sequence is equal to zero for all nonzero phase shifts. The peak factor of the proposed sequence set is √2, and the peak factor of a single trigonometric function is equal to √2. Assigning the sequences of the proposed set to a synthetic aperture ultrasonic imaging system would improve the S/N of the obtained image. The proposed sequence set can also improve the performance of radar systems. The performance of the applications of the proposed sequence sets are evaluated.