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Analysis of in-Plane Conductivity of La1-xSrxF3-x Superionic Thin Films

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Internet of Things, Smart Spaces, and Next Generation Networks and Systems (ruSMART 2015, NEW2AN 2015)

Abstract

Electrical properties of thin films of La1-xSrxF3-x solid solutions with x = 0 ÷ 0.24 were measured in temperature range from RT to 300°C and wide frequency range from 10−1 to 106 Hz by impedance spectroscopy method. The spectrums of impedance were analyzed with equivalent circuits contain RC and Warburg parts. DC-conductivities were calculated from RC-circuit of impedance and activation energies determined from Arrhenius-Frenkel equation \( \sigma_{DC} T = \sigma_{0} e^{{\left( { - \frac{{E_{\sigma T} }}{kT}} \right)}} \). Diffusion coefficients and their temperature dependencies were determined from Warburg part of impedance for different SrF2 content.

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References

  1. Sher, A., Solomon, R., Lee, K., Muller, M.W.: Phys. Rev. B 144(2), 594 (1966)

    Google Scholar 

  2. Lilly Jr., A.C., LaRoy, B.C., Tiller, C.O., Whiting, B.: Journal of the Electrochemical society 120(12), 1673 (1973)

    Google Scholar 

  3. Cheetham, A.K., et al.: Acta Crystallogr 32, 94 (1976)

    Google Scholar 

  4. Belzner, A., Schulz, H.: Zeitschrift fur Kristallographie 209, 239 (1994)

    Google Scholar 

  5. Sobolev, B.P., Sorokin, N.I.: Crystallography Reports, 59(6), 807–830 (2014)

    Google Scholar 

  6. Sorokin, N.I., Sobolev, B.P.: Crystallography reports 52(5), 842 (2007)

    Google Scholar 

  7. Sorokin, N.I., Fominykh, M.V., Krivandina, E.A., Zhmurova, Z.I., Sobolev, B.P.: Crystallography reports 41(2), 292 (1996)

    Google Scholar 

  8. Sorokin, N.I., Sobolev, B.P.: Physics of the Solid State 50(3), 416 (2008)

    Google Scholar 

  9. Vergentyev, T.Y., Koroleva, E.Y., Banshchikov, A.G., Sokolov, N.S., Chibisov, A.G.: Russian Journal of Electrochemistry 49(8), 783–787 (2013)

    Google Scholar 

  10. Kidner, N.J., Homrighaus, Z.J., Mason, T.O., Garboczi, E.J.: Thin Solid Films (496), 539 (2006)

    Google Scholar 

  11. Kidner, N.J., Meier, A., Homrighaus, Z.J., Wessels, B.W., Mason, T.O., Garboczi, E.J.: Thin Solid Films (515), 4588 (2007)

    Google Scholar 

  12. Vergent’ev, T.Y., Koroleva, E.Y., Kurdyukov, D.A., Naberezhnov, A.A., Filimonov, A.V.: Physics of the Solid State 55(1), 175–180 (2013)

    Google Scholar 

  13. Ivanov-Schitz, A.K., Sorokin, N.I., Sobolev, B.P., Fedorov, P.P: Int. Symp. on Systems with Fast Ionic Transport. Bratislava, p. 99 (1985)

    Google Scholar 

  14. Murin, I.V., Glumov, O.V., Gunber, W.: Ionics 1, 274 (1995)

    Google Scholar 

  15. Drozhzhin, O.A., Vorotyntseva, M.A., Maduara, S.R., Khasanova, N.R., Abakumova, A.M., Antipov, E.V.: Electrochimica Acta 89, 262–269 (2013)

    Google Scholar 

  16. Oberschmidt, J., Lazarus, D.: Phys. Rev. B, 21(12), 5823 (1980)

    Google Scholar 

  17. Wurz, M.C., Shaganov, A., Rissing, L., Filimonov, A., Vakhrushev, S.: ECS Transactions 50(10), 147 (2012)

    Google Scholar 

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Correspondence to A. V. Filimonov .

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Vergentev, T.Y., Koroleva, E.Y., Rissing, L., Filimonov, A.V. (2015). Analysis of in-Plane Conductivity of La1-xSrxF3-x Superionic Thin Films. In: Balandin, S., Andreev, S., Koucheryavy, Y. (eds) Internet of Things, Smart Spaces, and Next Generation Networks and Systems. ruSMART NEW2AN 2015 2015. Lecture Notes in Computer Science(), vol 9247. Springer, Cham. https://doi.org/10.1007/978-3-319-23126-6_73

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  • DOI: https://doi.org/10.1007/978-3-319-23126-6_73

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  • Online ISBN: 978-3-319-23126-6

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