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Simultaneous Multicomponent Spectrophotometric Kinetic Determination by a Hybrid Intelligent Computing Method

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Artificial Intelligence and Computational Intelligence (AICI 2011)

Part of the book series: Lecture Notes in Computer Science ((LNAI,volume 7002))

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Abstract

The improved PLS regression algorithm was developed by adding a preprocessor based on DOSC and WPT for enhancing the ability in the extraction of characteristic information and the quality of regression. The kinetic intelligent computing approach that combines kinetic-catalytic method with DOSC-WPT-PLS does not require a detailed kinetic model of the chemical system to obtain the order of reaction and rate constants. No reference to this method has been found. A program (PDOSCWPTPLS) was designed to perform the simultaneous spectrophotometric kinetic determination of Mn (II), Ag (I) and Fe (III). The relative standard errors of prediction (RSEP) obtained for all components using DOSC-WPT-PLS, WPTPLS and PLS were compared for evaluating their predictive capability. Experimental results demonstrated that the DOSC-WPT-PLS method had the best performance among the three methods and the results delivered by DOSC-WPT-PLS were significantly better.

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Authors and Affiliations

  1. Department of Chemistry, Inner Mongolia University, Huhhot, Inner Mongolia, China

    Ling Gao & Shouxin Ren

Authors
  1. Ling Gao
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  2. Shouxin Ren
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Editors and Affiliations

  1. School of Business Information Technology, RMIT University, City Campus, 124 La Trobe Street, 3000, Melbourne, VIC, Australia

    Hepu Deng

  2. School of Electronics and Information, Tongji University, 201804, Shanghai, China

    Duoqian Miao

  3. School of Computer and Information Engineering, Shanghai University of Electric Power, 200090, Shanghai, China

    Jingsheng Lei

  4. Department of Business Administration, Caritas Institute of Higher Education, 18 Chui Ling Road, Tseung Kwan O, Hong Kong, China

    Fu Lee Wang

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© 2011 Springer-Verlag Berlin Heidelberg

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Gao, L., Ren, S. (2011). Simultaneous Multicomponent Spectrophotometric Kinetic Determination by a Hybrid Intelligent Computing Method. In: Deng, H., Miao, D., Lei, J., Wang, F.L. (eds) Artificial Intelligence and Computational Intelligence. AICI 2011. Lecture Notes in Computer Science(), vol 7002. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-23881-9_46

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  • DOI: https://doi.org/10.1007/978-3-642-23881-9_46

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-23880-2

  • Online ISBN: 978-3-642-23881-9

  • eBook Packages: Computer ScienceComputer Science (R0)

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