Abstract
A circular steering propulsion mechanism is proposed to explore autonomous movement of a miniature micro-vehicle with singular off-center nanoengine. The micro-vehicle comprising of gold, nickel, and platinum is invented and synthesized by layer-by-layer deposition based on the micro-electro-mechanical systems technology. The self-steering propulsion of the gold–nickel–platinum micro-vehicle is characterized in deionized water at three different hydrogen peroxide concentrations. Experimental results demonstrate that the micro-vehicle autonomously propels forward circularly in either a clockwise or a counter-clockwise direction without any external control. This research sheds light on the exploration of the self-steering propulsion achieved by the micro-vehicle with singular off-center nanoengine.
Similar content being viewed by others
References
Astorga, S.E., Hu, L.X., Marsili, E., Huang, Y.: Electrochemical signature of escherichia coli on nickel micropillar array electrode for early biofilm characterization. ChemElectroChem 6, 4674–4680 (2019)
Astorga, S.E., Hu, L.X., Marsili, E., Huang, Y.: Ordered micropillar array gold electrode increases electrochemical signature of early biofilm attachment. Mater. Des. 185, 108256 (2020)
Bao, J., Yang, Z., Nakajima, M., Shen, Y., Takeuchi, M., Huang, Q., Fukuda, T.: Self-actuating asymmetric platinum catalytic mobile nanorobot. IEEE Trans. Robot. 30, 33–39 (2014)
Gao, W., Dong, R.F., Thamphiwatana, S., Li, J.X., Gao, W.W., Zhang, L.F., Wang, J.: Artificial micromotors in the mouse’s stomach: a step toward in vivo use of synthetic motors. ACS Nano 9, 117–123 (2015)
Gibbs, J., Zhao, Y.P.: Catalytic nanomotors: fabrication, mechanism, and applications. Front. Mater. Sci. 5, 25–39 (2011)
Grüber, G., Manimekalai, M.S., Mayer, F., Müller, V.: The a subunit of the A1AO ATP synthase of methanosarcina mazei Gö1 contains two conserved arginine residues that are crucial for ATP synthesis. Biochem. Biophys. Acta Bioenerget 1837, 940–952 (2014)
Hall, S.B., Khudaish, E.A., Hart, A.L.: Electrochemical oxidation of hydrogen peroxide at platinum electrodes. Part 1. An adsorption-controlled mechanism. Electrochim. Acta 43, 579–588 (1998)
Hess, H., Bachand, G.D., Vogel, V.: Powering nanodevices with biomolecular motors. Chem. Eur. J. 10, 2110–2116 (2004)
Hu, L.X., Miao, J.M., Grüber, G.: Disk-like nanojets with steerable trajectory using platinum nozzle nanoengines. RSC Adv. 6, 3399–3405 (2016a)
Hu, L.X., Tao, K., Miao, J.M., Grüber, G.: Hydrogen-peroxide-fuelled platinum–nickel-SU-8 microrocket with steerable propulsion using an eccentric nanoengine. RSC Adv. 6, 102513–102518 (2016b)
Hu, L.X., Miao, J.M., Grüber, G.: Temperature effects on disk-like gold-nickel-platinumnanoswimmer’s propulsion fuelled by hydrogen peroxide. Sens. Actu B 239, 586–596 (2017a)
Hu, L.X., Wang, N., Miao, J.M., Grüber, G.: Investigation of temperature dependency on the propulsion of disk-like nanoswimmers. Procedia Technol. 6, 48–50 (2017b)
Hu, L.X., Rehman, S., Tao, K., Miao, J.M.: Characterization on three-dimensional trajectory of disk-like gold–nickel–platinum nanomotor using digital holographic imaging. Chem Sel 3, 9634–9640 (2018)
Hu, L.X., Tao, K., Lim, Y.D., Miao, J.M., Kim, Y.J.: Self-steerable propulsion of disk-like micro-craft with dual off-center nanoengines. ACS Appl. Energy Mater. 2, 1657–1662 (2019)
Hu, L.X., Wang, N., Lim, Y.D., Miao, J.M.: Chemical reaction dependency, magnetic field and surfactant effects on the propulsion of disk-like micromotor and its application for E. coli transportation. NanoSelect (2020). https://doi.org/10.1002/nano.202000024
Hu LX, Wang N, Tao K, Catalytic micro/nanomotors: propulsion mechanisms, fabrication, control and applications. In: Smart nanosystems for biomedicine, optoelectronics and catalysis, Shabatina T, Editors, London, UK, Intechopen, 2020, pp. 1–33, doi: https://doi.org/10.5772/intechopen. 90456.
Kim, K., Guo, J.H., Liang, Z.X., Zhu, Q.F., Fan, D.L.: Man-made rotary nanomotors: a review of recent developments. Nanoscale 8, 10471 (2016)
Kline, T.R., Paxton, W.F., Mallouk, T.E., Sen, A.: Catalytic nanomotors: remote-controlled autonomous movement of striped metallic nanorods. Angew. Chem. Int. Ed. 44, 744–746 (2005)
Li, J., Huang, G., Ye, M., Li, M., Liu, R., Mei, Y.: Dynamics of catalytic tubular microjet engines: dependence on geometry and chemical environment. Nanoscale 3, 5083–5089 (2011)
Li, J., Xiao, Q., Jiang, J.Z., Chena, G.N., Sun, J.J.: Au–Fe/Ni alloy hybrid nanowire motors with dramatic speed. RSC adv. 4, 27522–27525 (2014)
Li, T., Li, L., Song, W., Wang, L., Shao, G., Zhang, G.: Self-propelled multilayered microrockets for pollutants purification. ECS J. Solid State Sci. Technol. 4, S3016–S3019 (2015)
Manjare, M., Yang, B., Zhao, Y.P.: Bubble driven quasioscillatory translational motion of catalytic micromotors. Phys. Rev. Lett. 109, 128305 (2012)
Moo, G.S., Pumera, M.: Chemical energy powered nano/micro/macromotors and the environment. Chem. Eur. J. 20, 1–16 (2014)
Morales-Narváez, E., Guix, M., Medina-Sánchez, M., Mayorga, C.C., Martínez, A.M.: Micromotor enhanced microarray technology for protein detection. Small 10, 2542–2548 (2014)
Ozin, G.A.: Channel crossing by a catalytic nanomotor. ChemCatChem 5, 2798–2801 (2013)
Paxton, W.F., Sen, A., Mallouk, T.E.: Motility of catalytic nanoparticles through self-generated forces. Chem. Eur. J. 11, 6462–6470 (2005)
Safdar, M., Itkonen, T., Janis, J.: Bubble-propelled trimetallic microcaps as functional catalytic micromotors. RSC adv. 5, 13171–13174 (2015)
Sanchez, S., Solovev, A., Harazim, S., Deneke, C., Mei, Y., Schmidt, O.: Rolled-up nanotech on polymers: from basic perception to self-propelled catalytic microengines. Chem. Rec. 11, 367–370 (2011)
Schmidt, C., Vogel, V.: Molecular shuttles powered by motor proteins: loading and unloading stations for nanocargo integrated into one device. Lab Chip 10, 2195–2198 (2010)
Soler, L., Sánchez, S.: Catalytic nanomotors for environmental monitoring and water remediation. Nanoscale 6, 7175–7182 (2014)
Soler, L., Martínez-Cisneros, C., Swiersy, A., Sánchez, S., Schmidt, O.: Thermal activation of catalytic microjets in blood samples using microfluidic chips. Lab Chip 13, 4299–4303 (2013)
Stock, D., Namba, K., Lee, L.K.: Nanorotors and self-assembling macromolecular machines: the torque ring of the bacterial flagellar motor. Curr. Opin. Biotechnol. 23, 545–554 (2012)
Tao, K., Yi, H.P., Yang, Y., Chang, H.L., Wu, J., Tang, L.H., Yang, Z.S., Wang, N., Hu, L.X., Fu, Y.Q., Miao, J.M., Yuan, W.Z.: Origami-inspired electret-based triboelectric generator for biomechanical and ocean wave energy harvesting. Nano Energy 67, 104197 (2020)
Teo, W.Z., Pumera, M.: Fe(0) nanomotors in ton quantities (10(20) units) for environmental remediation. Chem. Eur. J. 22, 1–10 (2016)
Wang, J.: Can man-made nanomachines compete with nature biomotors? ACS Nano 3, 4–9 (2009)
Wang, J.: Nanomachines: fundamentals and applications. Wiley VCH, Weinheim (2013). ISBN 978-3-527-33120-8
Wang, S., Wu, N.: Selecting the swimming mechanisms of colloidal particles: bubble propulsion versus self-diffusiophoresis. Langmuir 30, 3477 (2014)
Wang, N., Kanhere, E., Tao, K., Hu, L.X., Wu, J., Miao, J.M., Triantafyllou, M.: Investigation of a thin-film quasi-reference electrode fabricated by combined sputtering-evaporation approach. Electroanalysis 31, 560–566 (2019)
Wilson, D.A., Nolte, R.J.M., Hest, J.C.M.: Autonomous movement of platinum-loaded stomatocytes. Nat. Chem. 4, 268–274 (2012)
Zhao, G.J., Ambrosi, A., Pumera, M.: Self-propelled nanojets via template electrodeposition. Nanoscale 5, 1319–1324 (2013)
Acknowledgement
This work was financially supported by the Ministry of Education Tier 2 (Grant No: MOE2011-T2-2-156; ARC 18/12), Singapore. We gratefully acknowledged Mr. Pek and Mr. Nordin in Micromachines Lab, School of Mechanical and Aerospace Engineering at Nanyang Technological University, for their kind help on the fabrication and SEM characterization of the micro-vehicles.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Hu, L., Wang, N., Tao, K. et al. Circular steering of gold–nickel–platinum micro-vehicle using singular off-center nanoengine. Int J Intell Robot Appl 5, 79–88 (2021). https://doi.org/10.1007/s41315-020-00146-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s41315-020-00146-z