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Nanocrystalline ZnO–SnO2 mixed metal oxide powder: microstructural study, optical properties, and photocatalytic activity

  • Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)
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Abstract

In this study, nanocrystalline ZnO–SnO2 mixed metal oxide powder was prepared by co-precipitation using Zn(CH3COO)2∙2H2O and SnCl4∙5H2O as precursor materials. The powder was characterized by X–ray diffraction, scanning electron microscopy, and Fourier transform infrared spectroscopy. Williamson–Hall method was used to evaluate the micro structural parameters of ZnO–SnO2 such as crystallite sizes and lattice strain. The photoluminescence property of the sample was studied at different temperatures (10–300 K). Results showed that the emission intensity decreases with temperature increasing. The photocatalytic activity at the gas–solid interface was assessed by monitoring the degradation of nitrogen oxides, a major atmospheric pollutant. The results show that the nanocrystalline ZnO–SnO2 mixed metal oxide powder exhibits higher and more stable photocatalytic activity against photocorrosion than ZnO alone.

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Authors and Affiliations

  1. Department of Physics, Faculty of Science, University of Guilan, Namjoo Ave, Po Box 41335–1914, Rasht, Iran

    Hossein Mahmoudi Chenari

  2. Laser Applications Research Group, Ton Duc Thang University, Ho Chi Minh City, Vietnam

    Reza Zamiri

  3. Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City, Vietnam

    Reza Zamiri

  4. Department of Materials and Ceramic Engineering (DEMaC), University of Aveiro, Campus de Santiago, Aveiro, 3810–193, Portugal

    David Maria Tobaldi, Mehdi Shabani, Avito Rebelo, João António Labrincha & José M. F. Ferreira

  5. Faculty of Civil Engineering, Ton Duc Thang University, Ho Chi Minh City, Vietnam

    Mehdi Shabani

  6. Physics Department (I3N), University Of Aveiro, Campus Universitario de Santiago, Aveiro, Portugal

    J. Suresh Kumar, S. A. Salehizadeh, M. P. F. Graça & M. J. Soares

Authors
  1. Hossein Mahmoudi Chenari
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  2. Reza Zamiri
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  3. David Maria Tobaldi
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  4. Mehdi Shabani
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  5. Avito Rebelo
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  6. J. Suresh Kumar
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  7. S. A. Salehizadeh
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  8. M. P. F. Graça
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  9. M. J. Soares
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Correspondence to Reza Zamiri.

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Mahmoudi Chenari, H., Zamiri, R., Maria Tobaldi, D. et al. Nanocrystalline ZnO–SnO2 mixed metal oxide powder: microstructural study, optical properties, and photocatalytic activity. J Sol-Gel Sci Technol 84, 274–282 (2017). https://doi.org/10.1007/s10971-017-4484-y

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  • DOI: https://doi.org/10.1007/s10971-017-4484-y

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